(1S)-(+)-3-Carene
- Product Name
- (1S)-(+)-3-Carene
- CAS No.
- 498-15-7
- Chemical Name
- (1S)-(+)-3-Carene
- Synonyms
- (+)-3-CARENE;(+)-3-Carene;(1S,6R)-3-Carene;()-3-Carene;(+)-car-3-ene;(+)-3-Δ-CARENE;(+)-D-3-Carene;Einecs 207-856-6;(1S)-(+)-3-CARENE;(1S)-(+)-car-3-ene
- CBNumber
- CB3208717
- Molecular Formula
- C10H16
- Formula Weight
- 136.23
- MOL File
- 498-15-7.mol
(1S)-(+)-3-Carene Property
- Melting point:
- 25°C (estimate)
- Boiling point:
- 170-172 °C(lit.)
- alpha
- 17 º (NEAT)
- Density
- 0.865 g/mL at 25 °C(lit.)
- vapor pressure
- 2.73hPa at 20℃
- refractive index
- n20/D 1.473
- Flash point:
- 131 °F
- storage temp.
- -20°C
- solubility
- soluble in Acetone,Ethanol,Benzene
- form
- liquid (clear)
- color
- clear very slightly yellow
- Odor
- sweet
- optical activity
- [α]20/D +17°, neat
- Water Solubility
- 3.7mg/L at 20℃
- Merck
- 14,1836
- BRN
- 1902767
- LogP
- 4.38 at 37℃
- CAS DataBase Reference
- 498-15-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S)-(498-15-7)
- EPA Substance Registry System
- Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S,6R)- (498-15-7)
Safety
- Hazard Codes
- Xi,N
- Risk Statements
- 10-50/53-43
- Safety Statements
- 36/37-60-61
- RIDADR
- UN 2319 3/PG 3
- WGK Germany
- 2
- RTECS
- FH8400000
- F
- 10-23
- HS Code
- 2902.19.0050
- HazardClass
- 3
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H317May cause an allergic skin reaction
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 21986
- Product name
- (+)-3-Carene
- Purity
- analytical standard
- Packaging
- 5ml
- Price
- $147
- Updated
- 2024/03/01
- Product number
- 00410590
- Product name
- (+)-3-δ-Carene
- Purity
- primary reference standard
- Packaging
- 100mg
- Price
- $314
- Updated
- 2023/06/20
- Product number
- CRM40416
- Product name
- (+)-3-Carene solution
- Purity
- certified reference material, 2000?μg/mL in methanol, ampule of 1?mL
- Packaging
- 1mL
- Price
- $159
- Updated
- 2022/05/15
- Product number
- C0047
- Product name
- (+)-3-Carene
- Purity
- >90.0%(GC)
- Packaging
- 25mL
- Price
- $24
- Updated
- 2024/03/01
- Product number
- C0047
- Product name
- (+)-3-Carene
- Purity
- >90.0%(GC)
- Packaging
- 500mL
- Price
- $76
- Updated
- 2024/03/01
(1S)-(+)-3-Carene Chemical Properties,Usage,Production
Uses
Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.
Production Methods
3-Carene is obtained exclusively by fractional distillation of certain turpentines.
Definition
ChEBI: A car-3-ene (3,7,7-trimethylbicyclo[4.1.0]hept-3-ene) that has S configuration at position 1 and R configuration at position 6.
General Description
(1S)-(+)-3-Carene is a monoterpene.
Chemical Reactivity
3-Carene readily undergoes autoxidation and resinification in air. Addition of pyrogallol or resorcinol as stabilizers is recommended. On treatment with peracetic acid in glacial acetic acid and subsequent saponification, 3-carene is oxidized to 3,4- caranediol. Pyrolysis at 300–580 ℃ in the presence of Fe(III) oxide on carriers gives p-cymene as the main product.
(1S)-(+)-3-Carene Preparation Products And Raw materials
Raw materials
Preparation Products
(1S)-(+)-3-Carene Suppliers
View Lastest Price from (1S)-(+)-3-Carene manufacturers
- Product
- (1S)-(+)-3-Carene 498-15-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kgs
- Release date
- 2020-02-13